Europe to test system that uses sunlight to break up plastics in wastewaterStaff Writer | November 8, 2017
Harnessing the sun's radiation to help rid the oceans of microplastics contamination is one of several technical innovations to be developed by a new EU-funded project.
Technology Similar in concept to photosynthesis
While exposure to sunlight can degrade plastics into harmless elements, it's a slow process.
In some cases plastics can take several years to decompose.
Joydeep Dutta, chair of the Functional Materials department at KTH, says this system will speed up that process by making more efficient use of available visible light and ultraviolet rays from the sun.
The system involves coatings with material of nano-sized semiconductors that initiate and speed up a natural process called photocatalytic oxidation, Dutta says.
In a test household, these nano material coated filter systems will be placed at the exit of wastewater from homes. Similarly, in wastewater treatment plants these devices will be used to initiate microplastics degradation after the classical treatments are completed.
The photocatalytist membranes were created in partnership with the Swedish company, PP Polymer AB.
Photocatalytic oxidation with titanium oxide and zinc oxide semiconductors has been used to convert volatile pollutants, oils and other substances into harmless elements such as water and CO2.
Similar in concept to photosynthesis, photocatalysis activates the breakup of compounds by exciting electrons, which then causes water molecules to split into their constituent parts, hydrogen and oxygen.
The material captures enough solar radiation from a minimum of available light to set off a reaction with the molecules of the plastic.
The radicals then exchange electrons with the atoms that comprise plastic molecules, effectively pulling these contaminants apart into harmless compounds of CO2 and water.
"The semiconductor material is able to excite the molecules and set off this process using the 40 percent of solar radiation that is visible light," Dutta says. ■